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Microbial fuel cell with high content solid wastes as substrates: a review

Qingliang Zhao,Hang Yu,Weixian Zhang,Felix Tetteh Kabutey,Junqiu Jiang,Yunshu Zhang,Kun Wang,Jing Ding

《环境科学与工程前沿（英文）》 2017年 第11卷 第2期 doi: 10.1007/s11783-017-0918-6

摘要： Fundamentals and configuration design of MFCs fueled by HCSW were reviewed. HCSWs including sewage sludge, biomass and biowaste treated in MFCs were summarized. HCSW based MFCs technologies covered the types of sediment, soil, wetland and plant. Activated sludge process and composting could be coupled with HCSW-MFCs. HCSW-MFCs could be applied in bioremediation and biosensing. With the increasing concern about the serious global energy crisis and high energy consumption during high content solid wastes (HCSWs) treatment, microbial fuel cell (MFC) has been recognized as a promising resource utilization approach for HCSW stabilization with simultaneous electrical energy recovery. In contrast to the conventional HCSW stabilization processes, MFC has its unique advantages such as direct bio-energy conversion in a single step and mild reaction conditions (viz., ambient temperature, normal pressure, and neutral pH). This review mainly introduces some important aspects of electricity generation from HCSW and its stabilization in MFC, focusing on: (1) MFCs with different fundamentals and configurations designed and constructed to produce electricity from HCSW; (2) performance of wastes degradation and electricity generation; (3) prospect and deficiency posed by MFCs with HCSW as substrates. To date, the major drawback of MFCs fueled by HCSW is the lower power output than those using simple substrates. HCSW hydrolysis and decomposition would be a major tool to improve the performance of MFCs. The optimization of parameters is needed to push the progress of MFCs with HCSW as fuel.

关键词： Microbial fuel cell     High content solid wastes     Substrate     Bioremediation     Biosensor    

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Recycling combustibles from aged municipal solid wastes (MSW) to improve fresh MSW incineration in Shanghai

Dezhen CHEN, Zhenzhen GUAN, Guangyu LIU, Tong ZHU, Gongming ZHOU,

《环境科学与工程前沿（英文）》 2010年 第4卷 第2期   页码 235-243 doi: 10.1007/s11783-010-0016-5

摘要： Aged municipal solid wastes (MSW) excavated from landfills and dumpsites were characterized to analyze their fraction composition, moisture content, and lower heat value (LHV). The necessity and feasibility of recycling combustibles from aged MSW to improve the incineration of fresh MSW were investigated. The results showed that combustibles in aged MSW were easily separated from other components and than LHV of the separated combustibles are higher than 11000 kJ/kg. The fresh MSW are of high moisture contents with average LHV below 6500 kJ/kg, making their stable combustion difficult to maintain in MSW incinerators. For both fresh MSW and aged MSW, plastics are the main contributor to their LHV. To improve incineration of fresh MSW that are characterized with low LHV, combustibles separated from aged MSW were made into refuse derived fuel (RDF) pellets and were then added to fresh MSW by 2% wt.– 5% wt. LHV variation and air supply resistance change of the MSW layer on the incinerator grate caused by the addition of RDF was checked, and no significant changes were found. No obvious difference was observed for the ‘burn-out time’ between RDF pellets and fresh MSW either. RDF made from aged MSW combustibles is found to be a promising auxiliary fuel to improve the incineration of fresh MSW, and aged MSW from old landfill cells and dumpsites can be finally disposed of jointly with fresh MSW by recycling combustible from the former to be co-incinerated with the latter in the incineration plants.

关键词： aged municipal solid wastes (MSW)     fresh MSW     lower heat value (LHV)     combustibles     refuse derived fuel (RDF)     incineration    

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Utilization of waste vanadium-bearing resources in the preparation of rare-earth vanadate catalysts for semi-hydrogenation of ,-unsaturated aldehydes

《化学科学与工程前沿（英文）》 2022年 第16卷 第12期   页码 1793-1806 doi: 10.1007/s11705-022-2191-x

摘要： Recycling industrial solid waste not only saves resources but also eliminates environmental concerns of toxic threats. Herein, we proposed a new strategy for the utilization of petrochemical-derived carbon black waste, a waste vanadium-bearing resource (V > 30000 ppm (10 −6)). Chemical leaching was employed to extract metallic vanadium from the waste and the leachate containing V was used as an alternative raw material for the fabrication of vanadate nanomaterials. Through the screening of various metal cations, it was found that the contaminated Na+ during the leaching process showed strong competitive coordination with the vanadium ions. However, by adding foreign Ce3+ and Y3+ cations, two rare-earth vanadates, viz., flower-like CeVO4 and spherical YVO4 nanomaterials, were successfully synthesized. Characterization techniques such as scanning electron microscopy, transmission electron microscopy, X-ray diffraction, energy-dispersive X-ray spectroscopy, Fourier-transform infrared, and N2 physisorption were applied to analyze the physicochemical properties of the waste-derived nanomaterials. Importantly, we found that rare-earth vanadate catalysts exhibited good activities toward the semi-hydrogenation of α,β-unsaturated aldehydes. The conversion of cinnamaldehyde and cinnamic alcohol selectivity were even higher than those of the common CeVO4 prepared using pure chemicals (67.2% vs. 27.7% and 88.4% vs. 53.5%). Our work provides a valuable new reference for preparing vanadate catalysts by the use of abundant vanadium-bearing waste resources.

关键词： petrochemical solid wastes     vanadium recovery     resource utilization     nanomaterials     semi-hydrogenation    

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Characteristics of the stabilized/solidified municipal solid wastes incineration fly ash and the leaching

Yan SHAO,Haobo HOU,Guangxing WANG,Sha WAN,Min ZHOU

《环境科学与工程前沿（英文）》 2016年 第10卷 第1期   页码 192-200 doi: 10.1007/s11783-014-0719-0

摘要： Fly ash is a hazardous byproduct of municipal solid wastes incineration (MSWI). An alkali activated blast furnace slag-based cementitious material was used to stabilize/solidify the fly ash at experimental level. The characteristics of the stabilized/solidified fly ash, including metal leachability, mineralogical characteristics and the distributions of metals in matrices, were tested by toxic characteristic leaching procedure (TCLP), X-ray diffraction (XRD) and scanning electron microscopy-energy dispersive spectrometer (SEM-EDS) respectively. Continuous acid extraction was utilized to extract metal ions and characterize their leaching behavior. The stabilization/solidification procedure for MSWI fly ash demonstrates a strong fixing capacity for the metals by the formation of C-S-H phase, hydrated calcium aluminosilicate and ettringite. The stabilized/solidified fly ash shows a dense and homogeneous microstructure. Cr is mainly solidified in hydrated calcium aluminosilicate, C-S-H and ettringite phase through physical encapsulation, precipitation, adsorption or substitution mechanisms, and Pb is mainly solidified in C-S-H phase and absorbed in the Si-O structure.

关键词： municipal solid waste incineration (MSWI) fly ash     blast furnace slag     leaching behavior     Cr     Pb    

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Systematical strategies for wastewater treatment and the generated wastes and greenhouse gases in China

Jingbo GUO, Fang MA, Yuanyuan QU, Ang LI, Liang WANG

《环境科学与工程前沿（英文）》 2012年 第6卷 第2期   页码 271-279 doi: 10.1007/s11783-011-0328-0

摘要： China now faces double challenges of water resources shortage and severe water pollution. To resolve Chinese water pollution problems and reduce its impacts on human health, economic growth and social development, the situation of wastewater treatment was investigated. Excess sludge and greenhouse gases (GHGs) emitted during wastewater treatment were also surveyed. It is concluded that Chinese water pollution problems should be systematically resolved with inclusion of wastewater and the solid waste and GHGs generated during wastewater treatment. Strategies proposed for the wastewater treatment in China herein were also adequate for other countries, especially for the developing countries with similar economic conditions to China.

关键词： wastewater treatment     solid waste     greenhouse gases     systematical strategies    

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三种固体废弃物综合利用的研究

张万钧,郭育文,黄明勇,王斗天,张民胜

《中国工程科学》 2002年 第4卷 第10期   页码 62-66

摘要：

文章从环境建设的可持续发展出发，结合天津开发区在基础设施及园林绿化建设中面临土源紧缺的现实，将周边地区大量存在的海湾泥、粉煤灰、碱渣土等废弃物配制成一种新型种植基质以代替农田客土，并对其理化性质和对植物的适宜性进行了详细的试验研究。实验及推广结果表明海湾泥与碱渣土或粉煤灰按3∶1比例混合最适宜，同时该配比基质在土壤改良和植物适宜性方面均优于滨海盐土，其综合效益十分显著。

关键词： 固体废弃物     新土源     海湾泥     碱渣土     粉煤灰    

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Hydrothermal treatment of MSWI fly ash for simultaneous dioxins decomposition and heavy metal stabilization

Jinlong XIE, Yuyan HU, Dezhen CHEN, Bin ZHOU,

《环境科学与工程前沿（英文）》 2010年 第4卷 第1期   页码 108-115 doi: 10.1007/s11783-010-0013-8

摘要： Researches on the hydrothermal treatment of municipal solid waste incineration (MSWI) fly ash were conducted to eliminate dioxins and stabilize heavy metals. In order to enhance decomposing polychlorinated dibenzo-dioxins (PCDDs) and polychlorinated dibenzo-furans (PCDFs) during hydrothermal process, a strong reductant carbohydrazide (CHZ) is introduced. A hydrothermal reactor was set up by mixing raw MSWI fly ash or the pre-treated fly ash with water and then heated to a pre-set temperature; CHZ was spiked into solution according to specially defined dosage. Experimental results showed that under the temperatures of 518K and 533K, the decomposition rates of PCDDs/PCDFs were over 80% and 90%, respectively, by total concentration. However, their toxic equivalent (TEQ) decreased only slightly or even increased due to the rising in concentration of congeners 2, 3, 7, 8-TCDD/TCDF, which might be resulted from the highly chlorinated congeners losing their chlorine atoms and being degraded during the hydrothermal process. Better results of TEQ reduction were also obtained under the higher tested temperature of 533K and reactor with addition of 0.1%wt CHZ was corresponded to the best results. Good stabilization of heavy metals was also obtained in the same hydrothermal process especially when ferrous sulphate was added as auxiliary agent.

关键词： municipal solid wastes incineration (MSWI)     fly ashes     polychlorinated dibenzo-dioxins (PCDDs)     polychlorinated dibenzo-furans (PCDFs)     hydrothermal     heavy metal stabilization    

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Theoretical research and application of petrochemical Cyber-physical Systems

Jiming WANG

《工程管理前沿（英文）》 2017年 第4卷 第3期   页码 242-255 doi: 10.15302/J-FEM-2017053

摘要： A petrochemical smart factory is a green, efficient, safe and sustainable modern factory that combines cutting-edge information and communication technology with petrochemical advanced technology and equipment. A Cyber-physical System (CPS) is the infrastructure of a petrochemical smart factory. Based on the future challenges of the petrochemical industry, this paper proposes the definition, connotation and framework of a petrochemical CPS and constructs a CPS system at the enterprise, unit and field levels, respectively. Furthermore, the paper provides theoretical support and implementation reference of a CPS in the petrochemical industry and other industries by investigating the construction practice of a multi-level CPS in the China Petrochemical Corporation (SINOPEC).

关键词： Cyber-physical System (CPS)     petrochemical industry     smart factory    

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Resource utilization of typical biomass wastes as biochars in removing plasticizer diethyl phthalate

《环境科学与工程前沿（英文）》 2023年 第17卷 第1期 doi: 10.1007/s11783-023-1605-4

摘要：

● Six largely produced agricultural biomass wastes were pyrolyzed into biochars.

关键词： Plastic pollution     Phthalic acid esters     Designed biochar     Wetland plant     Adsorption    

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Enterprise-wide optimization of integrated planning and scheduling for refinery-petrochemical complex

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1516-1532 doi: 10.1007/s11705-022-2283-7

摘要： This paper focuses on the integrated problem of long-term planning and short-term scheduling in a large-scale refinery-petrochemical complex, and considers the overall manufacturing process from the upstream refinery to the downstream petrochemical site. Different time scales are incorporated from the planning and scheduling subproblems. At the end of each discrete time period, additional constraints are imposed to ensure material balance between different time scales. Discrete time representation is applied to the planning subproblem, while continuous time is applied to the scheduling of ethylene cracking and polymerization processes in the petrochemical site. An enterprise-wide mathematical model is formulated through mixed integer nonlinear programming. To solve the problem efficiently, a heuristic algorithm combined with a convolutional neural network (CNN), is proposed. Binary variables are used as the CNN input, leading to the integration of a data-driven approach and classical optimization by which a heuristic algorithm is established. The results do not only illustrate the detailed operations in a refinery and petrochemical complex under planning and scheduling, but also confirm the high efficiency of the proposed algorithm for solving large-scale problems.

关键词： planning     scheduling     refinery-petrochemical     convolutional neural network     heuristic algorithm    

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DE based economic control chart design and application for a typical petrochemical process

Zhi LI, Feng QIAN, Wenli DU, Weimin ZHONG

《工程管理前沿（英文）》 2017年 第4卷 第3期   页码 348-356 doi: 10.15302/J-FEM-2017043

摘要： Petrochemical industry plays an important role in the development of the national economy. Purified terephthalic acid (PTA) is one of the most important intermediate raw materials in the petrochemical and chemical fiber industries. PTA production has two parts: -xylene (PX) oxidation process and crude terephthalic acid (CTA) hydropurification process. The CTA hydropurification process is used to reduce impurities, such as 4-carboxybenzaldehyde, which is produced by a side reaction in the PX oxidation process and is harmful to the polyester industry. From the safety and economic viewpoints, monitoring this process is necessary. Four main faults of this process are analyzed in this study. The common process monitoring methods always use and SPE statistic as control limits. However, the traditional methods do not fully consider the economic viewpoint. In this study, a new economic control chart design method based on the differential evolution (DE) algorithm is developed. The DE algorithm transforms the economic control chart design problem to an optimization problem and is an excellent solution to such problem. Case studies of the main faults of the hydropurification process indicate that the proposed method can achieve minimum profit loss. This method is useful in economic control chart design and can provide guidance for the petrochemical industry.

关键词： petrochemical     PTA     economic control chart design     process monitoring     DE algorithm    

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A Study of the Functional Mechanism of Petrochemical Engineering Construction Project Management

Ji-ming Wang

《工程管理前沿（英文）》 2014年 第1卷 第2期   页码 129-139 doi: 10.15302/J-FEM-2014020

摘要： This paper, proceeding from the project construction process, the management mode and the implementation way, makes an in-depth study of the environmental characteristics and the managerial elements of petrochemical engineering construction project, revealing the inherent laws, establishing a theoretical model, and proposing a theory of the mechanisms of construction project management; and presents profound revelations found for construction project management in petrochemical engineering in seven aspects, which can play a guiding role in improving the managerial performance of petrochemical construction project. The theory established proposes that: The construction project management in petrochemical engineering is a complex systematic process, formed of 5 phases and 55 sub-processes of management, and exposed to many factors of influence; the environmental characteristics and managerial elements exercise positive impacts on managerial performance, but different factors have different impacts and act in different ways on managerial performance; the managerial elements of petrochemical engineering construction project are tiered, transferable, systematic and quantifiable, and the role of managerial elements in the managerial performance can be systematically integrated, quantitatively explained and transferred in a multi-level way.

关键词： petrochemical engineering     construction project     project management     functional mechanism    

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Studies of ultrasound disintegration of residual sludge and its energy consumption in water treatment of petrochemical

SHEN Jinfeng, YIN Xuan, GU Heping, Lv Xiaoping

《化学科学与工程前沿（英文）》 2007年 第1卷 第4期   页码 395-398 doi: 10.1007/s11705-007-0072-y

摘要： To investigate the influence of ultrasound pretreatment on sludge anaerobic digestion, the ultrasound disintegration of residual sludge in water treatment of petrochemical plant was studied, and the mechanisms of ultrasound and medium were introduced. Experimental results indicate that ultrasound cavitation induces the rise of sludge temperature, which improves ultrasound disintegration on sludge. U1trasound pretreatment can advance observably the quantity of chemical oxygen demand in sludge supernatant fluid (SCOD), which increases with ultrasound intensity and sonication time. The degree of ultrasound disintegration increases with the specific energy input. When the specific energy input is l0 000 kJ/kg of total dry solids, the degree of ultrasonic sludge disintegration reaches 40%.

关键词： specific     supernatant     petrochemical     ultrasound intensity     temperature    

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Pollution of hazardous substances in industrial construction and demolition wastes and their multi-path

Sheng Huang, Xin Zhao, Yanqiu Sun, Jianli Ma, Xiaofeng Gao, Tian Xie, Dongsheng Xu, Yi Yu, Youcai Zhao

《环境科学与工程前沿（英文）》 2017年 第11卷 第1期 doi: 10.1007/s11783-017-0901-2

摘要： Pollution pattern of metals and organic pesticide in demolition waste is studied. Organophosphorus pesticide can be everlasting on surface of demolition waste. Leaching potential of pollutants from simulated and onsite waste varies spatially. Direct oral and dermal ingestion, leaching potential into water exceed the limit. Implications for demolition waste management in industrial plants are proposed. Exploration of heavy metals and organic pollutants, their leaching capacity along with health and environmental risks in contaminated industrial construction and demolition waste (ICDW) within a pesticide manufacturing plant were investigated. A maximum content of 90.8 mg·kg Cd was found present in the wastes, which might originate from phosphorus rocks and industrial sulfuric acid used in pesticide production processes. An average concentration of 979.8 mg·kg dichlorovos and other 11 organophosphorus pesticide were also detected. Relatively high leaching rates of around 4.14‰ were obtained from laboratory simulated ICDW using both glacial acetic acid- sodium hydroxide and deionized water. Pesticide pollutants had the strongest tendency to retaining on dry bricks (leaching rate 1.68‰) compared to mortar-coatings, etc. due to their different physical characteristics and octanol-water partioning coefficient. Mobility of pesticide from on-site ICDW by water was spatially correlated to waste types, process sections and human activities, with a flux of leaching rate between 5.9‰ to 27.4%. Risk-based corrective action (RBCA) model was used to simulate the risk of contaminated ICDW debris randomly scattered. Oral and dermal ingestion amount by local workers was 9.8 × 10 and 1.9 × 10 mg·(kg·d) , respectively. Potential leaching risk to aquatic systems exceeded the limit for nearly 75% waste. Environmental and health risk exceedance was found in most ICDW, while the risk value of the most severely contaminated brick waste was 660 times beyond critical level. Implications for waste management involving construction and deconstruction work, waste transferring and regulation supplying were also provided.

关键词： Industrial demolition wastes     Heavy metals     Pesticides     Leaching characteristics     Risk assessment     Waste management    

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发展中的中国石化技术

袁晴棠

《中国工程科学》 2003年 第5卷 第12期   页码 43-47

摘要：

在概述中国石化工业现状的基础上，介绍了近年来中国石化技术的进展情况，并就新世纪初期中国石化技术的发展做了展望。

关键词： 石油化工     技术     发展     中国    

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标题 作者 时间 类型 操作

Microbial fuel cell with high content solid wastes as substrates: a review

Qingliang Zhao,Hang Yu,Weixian Zhang,Felix Tetteh Kabutey,Junqiu Jiang,Yunshu Zhang,Kun Wang,Jing Ding

期刊论文

Recycling combustibles from aged municipal solid wastes (MSW) to improve fresh MSW incineration in Shanghai

Dezhen CHEN, Zhenzhen GUAN, Guangyu LIU, Tong ZHU, Gongming ZHOU,

期刊论文

Utilization of waste vanadium-bearing resources in the preparation of rare-earth vanadate catalysts for semi-hydrogenation of ,-unsaturated aldehydes

期刊论文

Characteristics of the stabilized/solidified municipal solid wastes incineration fly ash and the leaching

Yan SHAO,Haobo HOU,Guangxing WANG,Sha WAN,Min ZHOU

期刊论文

Systematical strategies for wastewater treatment and the generated wastes and greenhouse gases in China

Jingbo GUO, Fang MA, Yuanyuan QU, Ang LI, Liang WANG

期刊论文

三种固体废弃物综合利用的研究

张万钧,郭育文,黄明勇,王斗天,张民胜

期刊论文

Hydrothermal treatment of MSWI fly ash for simultaneous dioxins decomposition and heavy metal stabilization

Jinlong XIE, Yuyan HU, Dezhen CHEN, Bin ZHOU,

期刊论文

Theoretical research and application of petrochemical Cyber-physical Systems

Jiming WANG

期刊论文

Resource utilization of typical biomass wastes as biochars in removing plasticizer diethyl phthalate

期刊论文

Enterprise-wide optimization of integrated planning and scheduling for refinery-petrochemical complex

期刊论文

DE based economic control chart design and application for a typical petrochemical process

Zhi LI, Feng QIAN, Wenli DU, Weimin ZHONG

期刊论文

A Study of the Functional Mechanism of Petrochemical Engineering Construction Project Management

Ji-ming Wang

期刊论文

Studies of ultrasound disintegration of residual sludge and its energy consumption in water treatment of petrochemical

SHEN Jinfeng, YIN Xuan, GU Heping, Lv Xiaoping

期刊论文

Pollution of hazardous substances in industrial construction and demolition wastes and their multi-path

Sheng Huang, Xin Zhao, Yanqiu Sun, Jianli Ma, Xiaofeng Gao, Tian Xie, Dongsheng Xu, Yi Yu, Youcai Zhao

期刊论文

发展中的中国石化技术

袁晴棠

期刊论文